Sulfides react with alkyl halides to give trivalent sulfonium salts, as in the case of trimethyl sulfonium bromide, (CH3)3S+Br, formed from dimethyl sulfide and methyl bromide. The sulfonium salts are named by putting the names of the several alkyl groups before “sulfonium halide.” Similarly, sulfoxides can be converted into the corresponding oxosulfonium salts, as in the case of trimethyl oxosulfonium chloride, [(CH3)3S=O]+Cl, converted from dimethyl sulfoxide and methyl chloride. Like sulfoxides, sulfonium and oxosulfonium salts are chiral and can be isolated in optically active form if the attached carbon groups are all different, as in RRRS+ and RRRS(=O)+.
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