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There is a large gap between pure gaseous phase and pure

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The thallium halides include monohalides, where thallium has oxidation state +1, trihalides where thallium generally has oxidation state +3 and some intermediate halides with mixed +1 and +3 oxidation states. These materials find use in specialized optical settings, such as focusing elements in research spectrophotometers. Compared to the more common zinc selenide based optics, materials such as thallium bromoiodide enable transmission at longer wavelengths.

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